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Since his earliest days as a detail man, Wimpe's expertise had been focused in cyclized ben-zylisoquinolines.
Docking of cyclized furin-Eda peptide (IIa) with furin P-domain (residue 487-560).
In fact our docking results identified a small segment 548VLEIENTSEA557 that interacts best with the cyclized Eda peptide (IIa).
The figure (left panel) shows the structures of furin-Eda peptide (II) and its cyclized form (IIa) following Bergman cyclo-aromatization reaction.
Expression of linear peptides bearing a cysteine-proline dipeptide sequence followed by glycolic acid results in self-rearrangement to a C-terminal diketopiperadine-thioester, which non-enzymatically generates a cyclized peptide.
We demonstrate the ribosomal synthesis of several naturally occurring backbone-cyclized peptides and a library based on a bicyclic scaffold, and we identify bioactive sequences by screening and deconvolution.
a series of brilliant investigations how the two carbon atoms of acetic acid are used for the synthesis of a long hydrocarbon with thirty carbon atoms, squalene, which in turn is cyclized in a novel type of reaction to a steroid with thirty carbon atoms, lanosterol.
548VLEIENTSEA557 showing its strong interaction with cyclized furin-Eda-peptide (IIa) (shown in red).