Definitions
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- noun organic chemistry The
cyclic ketone derived fromcyclopentane by formal replacement of twohydrogen atoms by anoxygen atom; anyderivative of this compound
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Cyclopentanone monooxygenase 1.14.13.16 1 Nomenclature EC number 1.14.13.16 Systematic name cyclopentanone, NADPH: oxygen oxidoreductase (5-hydroxylating, lactoniz - ing) Recommended name cyclopentanone monooxygenase Synonyms cyclopentanone oxygenase CAS registry number
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Zewail studied this reaction by exciting cyclopentanone molecules with
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The purification of cyclopentanone oxygenase from Pseudomonas N. C.I.B.9872.
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Griffin, M.; Trudgill, P.W.: Purification and properties of cyclopentanone oxygenase of Pseudomonas NCIB 9872.
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< 1, 2 > [1-3, 5, 6] Specific activity (U/mg) 4. 3-5 [1, 2, 4] Km-Value (mM) (O2) [1, 4] 0.15 (cyclopentanone) [4] pH-Optimum 7-7. 5
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(cyclopentanone) [1, 17] Additional information < 1, 6 > [8, 17, 18] Ki-Value
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NCIB 9872 [6]) [6] 3 Reaction and Specificity Catalyzed reaction cyclopentanone + NADPH + H+ + O2 = 5-valerolactone + NADP+ + H2 O Reaction type oxidation redox reaction reduction Natural substrates and products S cyclopentanone + NADPH +
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